Thanks so much for your post - sorry to understand that you are having some issues with your billing at the moment.
If it has gone from your bank account, there should be no reason as to why this would not be processed at this end for you. This will not update on your online account until your next bill is produced though.
I'll be more than happy to check and confirm this for you via Private Message; I have located your account from your Forum information so we just need to go through some security.
Please look out for the purple envelope in the top right of the page and pop me a reply when you can.